Here is another interesting aspect of plant nutrition drawn from the October 23 Soil Fertility Short Course at UC Davis.

Phosphorous (P), an essential element for plants, does not occur alone in nature and rather it combines with oxygen and hydrogen. Bonded with four oxygen atoms P makes phosphate, and when bonded with three atoms of oxygen and one atom of hydrogen, P forms phosphite.

The fully oxidized phosphate (the one with four oxygen atoms) is the most stable form of P in the environment, and is preferentially taken up by microbes and plant roots. Then again, phosphate is adsorbed to soil particles more than phosphite, meaning it is less available.  However, it does not necessarily follow that this enhanced availability of P via phosphite results in more uptake by plants, but even so, fertilizer formulations of phosphite plus calcium, magnesium or potassium have been formulated with the intent of taking advantage of this greater solubility in the soil.

Several studies examining a greater availability of P through phosphite have found that when phosphite is applied at an equivalent rate of P to phosphate fertilizer, it consistently underperformed when measured in terms of crop productivity, especially in the first year of cropping. In the way of explanation, the slower oxidation process of phosphite to the plant-root preferred phosphate, may be part of the equation of why the phosphite is not as effective as phosphate, in spite of having greater mobility.

In lay terms we can say, yes, phosphite might more available to plants in the soil, but they don’t want it as much as they want phosphate.

On the other hand, foliar applications of phosphite have shown that, while it can be converted to phosphate on the leaves by microbes living there, it is more readily absorbed into the foliage of some crop plants like citrus and avocados.   Phosphite application (usually once at pre-bloom and perhaps a second time later in the season) to the foliage of avocados or oranges has resulted in more flowers, greater fruit yield and size, total soluble solids and anthocyanin concentrations.

For further reading, see the paper below, which among other things implies that the positive results experienced in oranges and avocados could be replicated in berries…

http://www.spectrumanalytic.com/support/library/pdf/Phosphite_Fertilizers_What%20are%20they.pdf